Assistant Professor
Tel: (+302610) 997732
Web Page: http://www.chem.upatras.gr/faculty/lalioti
List of Publications:
Contact hours: Monday 13:00-14:00
Curriculum Vitae
2005-2007: Interdepartmental Master's Degree in Medicinal Chemistry: “Design and Development of Pharmaceutical Products” (MSc.), Department of Chemistry & Pharmacy, University of Patras, Greece, thesis title: "Synthesis, Study and Bioactivity Tests of Cu(II) Complexes with Imidazole Substituents", (Supervisor: G. Pairas, Associate Professor, Department of Pharmacy, University of Patras)
1996-2000: PhD in Inorganic Chemistry, Chemistry Department, University of Patras, Greece
Thesis title: "Study of Ternary Systems Zn(II)/RCO2-/N-donors: Contribution to Bioinorganic Chemistry and Chemistry of Molecular Materials", (Supervisor: Professor E. Manesi-Zoupa, Department of Chemistry, University of Patras)
1990-1995: BSc in Chemistry, Chemistry Department, University of Patras, Greece
Undergraduate research thesis title: “Synthesis and Characterization of Polynuclear Iron Compounds” (Supervisor: Prof. S. P. Perlepes, Department of Chemistry, University of Patras)
PREVIOUS POSITION(S)
2017-2022: Adjunct Faculty Member, Faculty of Science & Technology, Department of PHYSICAL SCIENCES", Hellenic Open University (HOU), Greece
2018-2021: Postdoctoral Researcher at the Institute of Chemical Engineering Sciences of the Foundation for Technology and Research, (FORTH/ICE-HT, Patras, Greece
2015-2021: (PD 407/80) Lecturer of Chemistry, Department of Pharmacy, University of Patras, Greece, Patras, Greece
2013-2015: Postdoctoral Researcher at the Chemistry Department, University of Patras, Greece
2001-2012:(PD 407/80) Lecturer of Chemistry, Departments of Chemistry and Materials Science, University of Patras, Greece
2000-2001: Postdoctoral Researcher at the Department of Chemistry, University of Florence, Italy
Books
“Theoretical Modelling of SMMs”, N. Lalioti, V. Tangoulis, Chapter in Book Single‐Molecule Magnets: Molecular Architectures and Building Blocks for Spintronics, (Wiley Edt.), September 2018
Granted patents
Research on United State patent US 2018/0251641 A1 with BIC Violex for Teflon/ graphene composite coatings
Courses
Undergraduate
Descriptive Inorganic Chemistry with lab exersises
Post-Graduate
Synthetic Methods and characterization of nanomaterials
Research Activities
- Molecular Inorganic Chemistry, with an emphasis on the synthesis, characterization, magnetic, optical, and catalytic study of complex compounds and polymers involving transition metals and lanthanides,
- Bioinorganic Chemistry, with an emphasis on the synthesis, characterization, and study of the structural and catalytic behavior of transition metal complexes as "models" of the active sites of various metalloenzymes and/or their antibacterial, anticancer activity.
- Chemistry of Magnetic Molecular Materials and Nanomaterials, with an emphasis on the synthesis and characterization of "hybrid" materials consisting of single-molecule magnets and "spin crossover" type compounds and graphene substrates or carbon nanotubes.
- Synthesis and characterization of various chemically modified graphene CMG nanomaterials
- She synthesized/studied the first Single Chain Magnet a molecular analogue of nanowires, during her Postdoctoral Research at the Department of Chemistry, University of Florence, Italy, with Prof. D. Gatteschi.
- The development of several synthetic strategies (conventional, solvothermal/hydrothermal, nano synthesis, reverse micelles colloids) for the isolation of new molecular inorganic compounds and "hybrid" molecular-nanomaterials and the study of magnetic phenomena arising from the cooperative interactions of the individual carriers.
Representative Publications
- “A nonsymmetric Dy2 single-molecule magnet with two relaxation processes triggered by an external magnetic field: a theoretical and integrated EPR study of the role of magnetic-site dilution”, N. Lalioti, V. Nastopoulos, N. Panagiotou, A. Tasiopoulos, J. van Slageren, P. Zhang, G. Rajaraman, V. Tangoulis, Dalton Trans., 51, 1985-1994, 2022 (10.1039/D1DT04089H)
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“2-D spin crossover materials at the nanometric scale: the effects of the size-reduction on the magnetic properties”, Tangoulis, V., Polyzou, C. D., Gkolfi, P., Lalioti, N., Malina, O. & Polaskova, M., Dalton Trans. 50, 3109-3115, 2021 (10.1039/D1DT00250C) (review article)
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”Facile Method to Prepare pH-Sensitive PEI-Functionalized Carbon Nanotubes as Rationally Designed Vehicles for Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) Delivery” N. Lalioti, J. Parthenios, N. Langford, E. Valsami-Jones, C. Kakoulidou, G. Psomas, V. Bekiari”, C, 6, 62, 2020 (10.3390/c6040062)
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“Noncovalent Grafting of a Dy2III Single-Molecule Magnet onto Chemically Modified Multiwall Carbon Nanotubes”: V. Tangoulis, N. Lalioti, J. Parthenios, N. Boukos, O. Malina, J. Tucek, R. Zboric, Inorg. Chem., 57, 6391-6400, 2018 (10.1021/acs.inorgchem.8b00472)
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“Hydrothermal Synthesis and Characterization of 2D M(II)-Quinate (M = Co,Zn) Metal-Organic Lattice Assemblies: Solid-State Solution Structure Correlation in M(II)-Hydroxycarboxylate Systems”, M. Menelaou, A. Konstantopai, N. Lalioti, C.P. Raptopoulou, V. Psycharis, A. Terzis, C. Mateescu, K. Tsarhopoulos, P. Rigas and A. Salifoglou, Inorg. Chem., 49, pp. 11449-11462, 2010 (10.1021/ic1013945)
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“Metalloradical Complexes of Manganese and Chromium Featuring an Oxidatively Rearranged Ligand”, R. Çelenligil-Çetin, P. Paraskevopoulou, N. Lalioti, Y. Sanakis, R. J. Staples, N. P. Rath and P. Stavropoulos*, Inorg. Chem., 47, 10998-1009, 2008 (10.1021/ic801219u)
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“Oxidative Ligand Rearrangement Due to Incipient Aminyl Radicals in the Oxidation of Iron(II) Species with Dioxygen”, R. Çelenligil-Çetin, P. Paraskevopoulou, R. Dinda, N. Lalioti, Y. Sanakis, A. M. Rawashdeh, R. J. Staples, E. Sinn and P. Stavropoulos*, Eur. J. Inorg. Chem., 5, 673-677, 2008 (10.1002/ejic.200701297)
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XMCD for monitoring exchange interactions. The role of the Gd 4f and 5d orbitals in metal-nitronyl nitroxide magnetic chains Champion, G., Lalioti, N., Tangoulis, V., Arrio, M., Sainctavit, P., Villain, F., Caneschi, A., Gatteschi, D., Giorgetti, C., Baudelet, F., Verdaguer, M. & Moulin, C., Journal of the American Chemical Society, 125, 8371-8376, 2003 10.1021/ja034608u
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“High Nuclearity Nickel Compounds with three, four or five Metal Atoms Showing Antibacterial Activity” M. Alexiou, I. Tsivikas, C. Dendrinou-Samara, A.A. Pantazaki, P. Trikalitis, N. Lalioti, D.A. Kyriakidis* and D. P. Kessissoglou*, J. Biol. Chem., 93, 256-264, 2003. (10.1016/s0162-0134(02)00591-3)
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Cobalt(II)-Nitronyl Nitroxide Chains As Molecular Magnetic Nanowires”, A. Caneschi, D. Gatteschi*, N. Lalioti, C. Sangregorio, R. Sessoli, G. Venturi, A.Vindigni, A. Rettori, M. G. Pini, M. A. Novak, Ang. Chem. Int. Ed., 40, 1760-1763, 2001.(10.1002/1521-3773(20010504)40:9<1760::AID-ANIE17600>3.0.CO;2-U)